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<style>
body {
background-color:#ffffff;
}
body, .cfsbdyfnt {
font-family: 'Oswald', sans-serif;
font-size: 18px;
}
h1, h2, h3, h4, h5, h5, .cfsttlfnt {
font-family: 'Playfair Display', serif;
}
.panel-title { font-family: 'Oswald', sans-serif; }
</style>
<title></title>
<style id="sitestyles">
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.btn{border:2px solid;line-height:1.2;margin-left:10px;margin-right:10px}.btn-primary:hover{color:#fff!important}#site button,#site .btn,#site .btn-small,#site .btn-lg,#site .tmslider .btn{transition:all .8s ease;border-radius:25px;font-size:;padding:.5em .7em;letter-spacing:1px}#site .zonetools .btn,#site .edimg{transition:initial;border-radius:initial;font-size:14px;padding:2px 5px;letter-spacing:initial}#inbdy{max-width:1366px}.topstrip{color:#fff;background:#1b2a29;border-bottom:0 solid #379078}.topstrip .row{max-width:1366px;float:none;margin:auto}.topstrip a{color:#000}.topstrip a:hover{color:rgba(66,105,101,.85)}.topstrip .txttkn a{color:#426965}.topstrip .txttkn a:hover{color:rgba(66,105,101,.85)}.topstrip .addressitem{margin:20px 5px}@media (min-width:992px){.topstrip .addressitem .lbtel,.topstrip .addressitem .number,.topstrip .addressitem .vsep{display:none}.topstrip .addressitem [itemprop="streetAddress"]:after{content:" | "}}.topstrip 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a:hover{color:#426965!important;box-shadow:unset;border-left:5px solid #00a097;padding-left:15px;border-top:0 solid #609892}.navbar{background-color:#fff!important;border:0 solid #fff!important}.navbox{background-color:transparent!important}.js-clingify-locked .navbar{background-color:#fff!important;border:0 solid #fff!important}.js-clingify-locked .navbox{background-color:transparent!important}.navbarlocked{height:unset!important}.navbarlocked .dropdown-menu li a{background:#fff}#inhdr .upperbanner img{max-height:80px}@media (max-width:767px){#inhdr .upperbanner img{max-height:50px}}#strip{background:#fff!important}#strip [data-type="image"]{max-height:10em;overflow:hidden}#strip .page-title{text-shadow:none;background:rgba(66,105,101,.6)}#strip .page-title h1{color:#fff;margin:auto auto}@media (max-width:767px){#strip .page-title h1{font-size:}}.section-strip-item{color:#00a097!important}.section-strip-item a{color:#00a097!important}[data-typeid="inlinesearch"] input{border:1px solid #426965;border-radius:20px;height:40px;box-shadow:none;background:#3afff4;max-width:420px;float:right;margin:auto;margin-bottom:10px}[data-typeid="inlinesearch"] input .form-control{color:#fff!important}.homeobit-box{color:#000;padding-top:5px;padding-bottom:5px;max-width:1366px;float:none;margin:auto}.homeobit-box a,.homeobit-box a:hover,.homeobit-box p,.homeobit-box h1,.homeobit-box h2,.homeobit-box h3,.homeobit-box h4{color:#1b2a29!important}.homeobit-box .obpgimg{transition:all 2s ease!important;border-radius:10px!important}.homeobit-box .obphlst{transition:all 2s ease!important;border-radius:10px!important;padding:0px!important;margin-left:0;margin-right:0;box-shadow:0 0 0 #888!important;border:0 solid!important}.homeobit-box .obphlst:hover{transform:scale(1.2)}.homeobit-box .{padding-bottom:100%;padding-left:92%;margin:auto;border-radius:10px!important}.homeobit-box .form-control{background:rgba(255,255,255,.9)!important}.obslide{background:rgba(0,0,0,.1)}.obslide .details .obitdate{color:#fff!important}.obslide .details .obitdate a{color:#fff!important}.obitname,.obitdate{color:#379078}.obitname{font-weight:700;text-transform:uppercase}.horizobits{margin:0 }.glyphicon-chevron-right,.glyphicon-chevron-left{color:}.glyphicon-chevron-right:hover,.glyphicon-chevron-left:hover{color:}[data-typeid="locationmap"]{background:#609892}[data-typeid="locationmap"] iframe{border:none;filter:grayscale(1.9) sepia(2%) opacity(.85);transition:all 2s ease}[data-typeid="locationmap"] iframe:hover{filter:unset}[data-typeid="multimap"]{background:transparent}[data-typeid="multimap"] .multimap{border:0 solid #ccc;background:#609892}[data-typeid="multimap"] .multimap .leaflet-tile-pane{-webkit-filter:opacity(.85) grayscale(60%) brightness(1.1);-moz-filter:opacity(.85) grayscale(60%) brightness(1.1);filter:opacity(.85) grayscale(60%) brightness(1.1);transition:all .5s ease}[data-typeid="multimap"] .multimap:hover .leaflet-tile-pane{-webkit-filter:opacity(1) grayscale(0%) 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#ccc;border-radius:0;background:#eee;margin-top:5px}[data-typeid="multimap"] .multimap-location h4{color:#000;font-weight:700}[data-typeid="multimap"] .multimap-location:hover{background:radial-gradient(#fff,#eee);border-top:4px solid #888}[data-typeid="multimap"] .{background:rgba(238,238,238,.5);border-top:4px solid #c00}[data-typeid="multimap"] .multimap-location button{color:white;background:#888;border-radius:0;margin-bottom:10px}[data-typeid="multimap"] .multimap-location button:hover{background:mediumblue}.edgetoedge{margin-left:-100vw;margin-right:-100vw;margin-bottom:0;padding-left:100vw;padding-right:100vw;padding-top:5px;padding-bottom:5px}.edgetoedge .tools{margin-left:100vw;margin-right:100vw}.edgetoedge .inner .tools{margin-left:0vw;margin-right:0vw}.edgetoedge2{margin-left:-100vw;margin-right:-100vw;margin-bottom:0;padding-left:100vw;padding-right:100vw}.edgetoedge2 .tools{margin-left:100vw;margin-right:100vw}.edgetoedge2 .inner .tools{margin-left:0vw;margin-right:0vw}.pale-col{color:#000;background-color:!important}.color-col{background-color:#426965!important}.color-col p,.color-col h1,.color-col h2,.color-col h3,.color-col h4{color:#fff}.footer{background-color:#1b2a29!important}.footer [data-typeid="sitemap"] div a:nth-child(4){display:none}.footer p,.footer .addressitem{color:#fff}.footer h1,.footer h2,.footer h3,.footer h4,.footer .form-group{color:#b2e1d5}.footer a{color:#fff}.footer-box .row{padding:0}.footer-box .semiopaque{background-color:rgba(66,105,101,0);min-height:300px;animation:slideInUp 2s ease}.footer-box .semiopaque p,.footer-box .semiopaque h1,.footer-box .semiopaque h2,.footer-box .semiopaque h3,.footer-box .semiopaque h4{color:#fff}.sitemapsubitem{display:none}.sitemapitem{display:inline;padding:0}.panel-success .panel-heading{background-color:#426965!important}.panel-success .panel-title{color:#fff}.panel-success .panel-body{border-left:1px solid #426965!important;border-right:1px solid #426965!important;border-bottom:1px solid #426965!important}.cfsacdn .panel-title{background:transparent}.cfsacdn .panel-title a{color:#fff!important}.cfsacdn .panel-heading{background:#379078!important}.cfsacdn .panel{border-color:#379078!important}.cfsacdn .panel font{color:!important}.blackbg{background:#609892}.max1570{max-width:1570px!important;float:none!important;margin:auto!important}.max1470{max-width:1470px!important;float:none!important;margin:auto!important}.max1370{max-width:1370px!important;float:none!important;margin:auto!important}.max1270{max-width:1270px!important;float:none!important;margin:auto!important}.max1170{max-width:1170px!important;float:none!important;margin:auto!important}.site-credit .credit-text,.site-credit .credit-text a{background-color:transparent;color:#000}.obitlist-title a{color:#000}{color:}{color:#000}{color:#000}#popout-add h4,#popout-settings h4{color:#fff}.btn-danger{color:#fff!important;border-color:#5cb85c!important;background-color:#5cb85c!important}.btn-danger:hover{color:#5cb85c!important;background-color:#fff!important;border-color:#fff!important}.max1570{max-width:1570px!important;float:none!important;margin:auto!important}.max1470{max-width:1470px!important;float:none!important;margin:auto!important}.max1370{max-width:1370px!important;float:none!important;margin:auto!important}.max1270{max-width:1270px!important;float:none!important;margin:auto!important}.max1170{max-width:1170px!important;float:none!important;margin:auto!important}.upperbanner{background-color:#fff;padding-top:0;padding-bottom:5px;border-top:0 solid #379078;border-bottom:0 solid #379078}.upperbanner p{color:#000;animation:slideInLeft 2s ease}.upperbanner a{color:#426965}.upperbanner a:hover{color:rgba(66,105,101,.7)}.cta-box{background:#2e4a47!important}.cta-box p{color:#fff}.cta-box a{color:#fff}.cta-box a:hover{color:#379078}.js-clingify-locked .upperbanner{background-color:#fff;max-width:100vw;float:none;margin:auto}#outhdr .navbar{background:#fff;background:transparent}#outhdr .navbar a{color:#fff!important;border:0 solid transparent;transition:background-color .4s;transition:all .4s ease-in-out;padding-top:!important;padding-bottom:!important}#outhdr .navbar {font-weight:bold!important;letter-spacing:1px}@media (max-width:991px){#outhdr .navbar a{font-size:.75em!important}#outhdr .navbar {padding:25px 10px 20px 10px!important}}@media (max-width:767px){#outhdr .navbar a{padding-top:14px!important}}#outhdr .navbar a:hover{color:#426965!important;background:#d6f0e9!important;border:0 solid #379078}#outhdr .navbar .open a:hover{background-color:#fff!important}#outhdr .navbar .open {color:#426965!important;background-color:#d6f0e9!important}#outhdr .navbar .dropdown-menu{padding-top:0;padding-bottom:0;background:rgba(255,255,255,.95)!important}#outhdr .navbar .dropdown-menu li a{color:#426965!important;background:transparent!important;font-family:helvetica,sans-serif;font-size:.8em;padding-left:20px;padding-right:20px;padding-top:12px!important;padding-bottom:10px!important;text-transform:uppercase;border:0 solid #379078;border-left:0 solid transparent;transition:background-color .2s}#outhdr .navbar .dropdown-menu li a:hover{color:#fff!important;background:#8dd3c0!important;border:0 solid #379078;border-left:5px solid #379078;padding-left:15px}#outhdr .navbar {background:none!important;border:#fff!important;outline:#fff!important}#outhdr .navbar-brand{display:none!important}#outhdr .cfshznav{background:#426965}#outhdr .cfshznav .nav{padding:0 0 0 0}@media (max-width:991px){#outhdr .cfshznav .nav>:nth-child(4){display:none}}#outhdr .cfshznav .nav>:nth-child(4) a{color:rgba(255,255,255,0)!important;background:url();background-repeat:no-repeat;background-size:84%;width:240px;height:155px;color:rgba(255,255,255,0);font-size:0;background-position:center;padding-bottom:30px}#outhdr .cfshznav .nav>:nth-child(4) a:hover{background:url(),transparent!important;background-size:89%!important;background-repeat:no-repeat!important;background-position:center!important}#outhdr .cfshznav .nav>:nth-child(4):hover{background:transparent!important}#outhdr .js-clingify-locked{background:#426965!important}#outhdr .js-clingify-locked .navbar{background:#426965!important}#outhdr .js-clingify-locked .nav{padding:5px 0 0 0}#outhdr .js-clingify-locked .nav a{color:#fff!important;padding-top:2em!important;padding-bottom:!important;margin-bottom:0px!important}@media (max-width:991px){#outhdr .js-clingify-locked .nav>:nth-child(4){display:none}}#outhdr .js-clingify-locked .nav>:nth-child(4) a{color:rgba(255,255,255,0)!important;background:url(background:url();background-repeat:no-repeat;background-size:contain;width:150px;height:60px;color:rgba(255,255,255,0);font-size:0;margin-top:10px;background-position:center;margin-bottom:5px;border-radius:0%;bottom:0;padding-bottom:0}#outhdr .js-clingify-locked .nav>:nth-child(4):hover{background:transparent!important}.mobile-logo{background:#426965}@media (max-width:991px){.sidr-inner .sidr-class-nav>:nth-child(5){display:none}}.cta-box{background-color:#426965}.cta-box p{color:#fff}.cta-box a{color:#fff}.cta-box a:hover{color:#379078}[data-typeid="popoutnotice"] .popout-notice .widget-label{background:yellow;color:green;padding:10px}[data-typeid="popoutnotice"] .popout-notice .widget-label:after{content:""}.cfs-popout{background:linear-gradient(120deg,#2e4a47,#568883 120%)!important;color:#fff;max-width:280px;padding:10px;border:0;border-left:8px solid #379078;outline:0 solid rgba(255,255,255,.2);outline-offset:0;box-shadow: .25em 1em rgba(0,0,0,.1)}.cfs-popout .close{width:;height:;text-shadow:none;color:#fff;opacity:1;padding:5px;margin:3px;background:#90374f;border-radius:100%;border:1px solid rgba(255,255,255,.3);font-family:raleway,sans-serif;font-size:75%;z-index:1}.cfs-popout .content-area .title{border-bottom:1px solid rgba(255,255,255,.2);padding-bottom:10px;margin-top:2px;margin-bottom:10px;line-height:auto;opacity:1}.cfs-popout .content-area h3{font-weight:700;transition:all 1s ease;animation:pulse ease-in-out;animation-delay:3s}.cfs-popout .content-area h3:hover{text-shadow:0 0 2em #000}.cfs-popout .clickable{font-style:italic;border:1px solid #fff;display:inline-block;padding:4px 10px 6px;opacity:.5;transition:all .5s ease}.cfs-popout .clickable:hover{opacity:1}
#obitlist .row {
border: 0px;
border-bottom: 1px solid #a0fffa;
border-radius: 0px;
padding: 2em;
}
#obitlist .obphlst {
border-radius: 0px;
border: 0px solid #E0D9D9 !important;
padding: 0px;
box-shadow: 1px 1px 1px 1px rgba(50,50,50,0) !important;
background: #fff;
}
</style>
<style> #smart2881336973111-1 { color: !important; background-color: } #smart2881336973111-1:hover { color: !important; background-color: } #smart2881336973111-2 { color: !important; background-color: } #smart2881336973111-2:hover { color: !important; background-color: } #smart2881336973111-3 { color: !important; background-color: } #smart2881336973111-3:hover { color: !important; background-color: } </style>
<style scoped="">
#smart138401661026 .toplevel {
font-size: 15px;
padding: 20px 18px;
font-weight: normal;
}
#smart138401661026 .navbar-default .navbar-nav > li > a {
text-transform: uppercase;
}
</style>
<style>
/* Default arrow for menu items with submenus */
.sidr-class-dropdown > a::after {
content: '\25B6'; /* Unicode for a right-pointing triangle */
position: absolute;
right: 30px;
color: white;
transition: transform ;
}
/* Arrow rotates down when the submenu is open */
. > a::after {
content: '\25BC'; /* Unicode for a down-pointing triangle */
transform: rotate(0deg); /* Reset rotation */
}
/* Hide Sidr menu if the screen width is greater than 768px */
@media (min-width: 769px) {
#sidr-main-mn966128 {
display: none !important;
}
}
</style>
<style scoped="">
#smart3739698360101 .toplevel {
font-size: 15px;
padding: 20px 18px;
font-weight: normal;
}
#smart3739698360101 .navbar-default .navbar-nav > li > a {
text-transform: uppercase;
}
</style>
<style>
/* Default arrow for menu items with submenus */
.sidr-class-dropdown > a::after {
content: '\25B6'; /* Unicode for a right-pointing triangle */
position: absolute;
right: 30px;
color: white;
transition: transform ;
}
/* Arrow rotates down when the submenu is open */
. > a::after {
content: '\25BC'; /* Unicode for a down-pointing triangle */
transform: rotate(0deg); /* Reset rotation */
}
/* Hide Sidr menu if the screen width is greater than 768px */
@media (min-width: 769px) {
#sidr-main-mn184060 {
display: none !important;
}
}
</style>
<style> #smart2333938227047-1 { color: !important; background-color: } #smart2333938227047-1:hover { color: !important; background-color: } #smart2333938227047-2 { color: !important; background-color: } #smart2333938227047-2:hover { color: !important; background-color: } #smart2333938227047-3 { color: !important; background-color: } #smart2333938227047-3:hover { color: !important; background-color: } </style>
</head>
<body class="cs56-229">
<br>
<div id="site" class="container-fluid">
<div id="innersite" class="row">
<div id="block-outhdr" class="container-header dropzone">
<div class="row stockrow">
<div id="outhdr" class="col-xs-12 column zone">
<div class="inplace top-border" data-type="struct" data-typeid="FullCol" data-desc="Full Col" data-exec="1" id="struct1326593510923" data-o-bgid="" data-o-bgname="" data-o-src="">
<div class="row">
<div class="col-sm-12 column ui-sortable">
<div class="inplace cta-box" data-type="struct" data-typeid="FullCol" data-desc="Full Col" data-exec="1" id="struct735952154750">
<div class="row">
<div class="col-sm-12 column ui-sortable">
<div class="inplace" data-type="struct" data-typeid="Thirds2-1" data-desc="Thirds 2-1" data-exec="1" id="struct5203190405039">
<div class="row">
<div class="col-xs-4 column ui-sortable">
<div class="inplace pad-left pad-right smallmedia text-center pad-top pad-bottom" data-type="smart" data-typeid="socialmedia" data-desc="Social Media & Links" data-rtag="socialmedia" id="smart2881336973111" data-itemlabel="">
<div class="smbuttons"> <span class="btn btn-social btn-facebook"></span>
</div>
</div>
</div>
</div>
</div>
</div>
</div>
</div>
<div class="inplace hidden-md hidden-lg mobile-logo" data-type="struct" data-typeid="ThreeCols" data-desc="Three Cols" data-exec="1" id="struct361897052728" data-o-bgid="" data-o-bgname="" data-o-src="" style="">
<div class="row">
<div class="col-sm-4 column ui-sortable"></div>
<div class="col-sm-4 col-xs-4 column ui-sortable">
<div class="inplace pad-left pad-right hidden-md hidden-lg pad-top pad-bottom" data-type="image" data-typeid="site" data-desc="Site Image" id="image3805680664636" style="" data-itemlabel=""><img alt="site image" class="img-responsive" src="" style="">
<div contenteditable="false" style="height: 0px;"></div>
</div>
</div>
<div class="col-sm-4 col-xs-8 column ui-sortable">
<div class="inplace menu-ip hidden-sm hidden-md hidden-lg transparent-menu" data-type="smart" data-typeid="menu" data-desc="Menu Bar" data-exec="1" data-rtag="menu" id="smart138401661026" data-itemlabel="" style="position: relative; z-index: 30; left: 0px; top: 0px;" data-rsttrans="1">
<div style="position: relative; z-index: 3;">
<div class="cfshznav" id="navbar-mn966128">
<div class="navbar cfsbdyfnt navbar-default" role="navigation"><br>
<div id="mn966128" class="navbar-collapse collapse mnujst centered">
<ul class="nav navbar-nav mnujst centered">
<li id="li-1-2" class="dropdown navbox"><span class="dropdown-toggle toplevel navlink ln-listings"></span>
<ul class="dropdown-menu">
<li class="navbox" id="li-1-2-0">
<span class="navlink ln-listings">Birch reduction ncert. and liquid ammonia is called Birch reduction.</span>
</li>
<li class="navbox" id="li-1-2-1">
<span class="navlink ln-listings"><br>
</span>
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<span class="dropdown-toggle toplevel navlink ln-about-us">Birch reduction ncert This is done using dry ice or acetone cold finger, which is equipment in which the coolant (dry ice or acetone) flows, and helps create a localized cold area. Pd supported over CaCO 3 or BaSO 4 and partially poisoned by addition of sulphur or quinoline. Ans: Hint: For identifying the correct product of the toluene firstly we have to study about the Birch reduction and then we have to write the whole reaction of toluene (Benzene with Birch’s Reduction Mechanism. and liquid ammonia is called Birch reduction. e. Arndt-Eistert reduction Hydrocarbons Chemistry Practice questions, MCQs, Past Year Questions (PYQs), NCERT Questions, Question Bank, Class 11 and Class 12 Questions, NCERT Exemplar Questions and PDF Questions with answers, solutions, explanations, NCERT reference and difficulty level Example: Reduction of Alkynes using Lindlar’s Catalyst. Doubtnut is No. Number of active methylene hydrogens present in X=a and in Y=b . involved in a double bond. , but electron with drawing groups are not on the . Jul 21, 2023 · Step by step video solution for Birch reduction of toluene leads to a product with molecular formula C_(7)H_(10). Formation of Product: - The reduction of But-2-yne leads to the formation of trans-But-2-ene (CH₃CH=CHCH₃). Example: Dehydrohalogenation of Alkenes: Fisher-Spier reduction 3. Oct 17, 2019 · The Birch Reduction is a process for converting benzene (and its aromatic relatives) to 1,4-cyclohexadiene using sodium (or lithium) as a reducing agent in liquid ammonia as solvent (boiling point: –33°C) in the presence of an alcohol such as ethanol, methanol or t-butanol. Sc. The mechanism for the NCERT Solutions For Class 12. Sodium or lithium metal in liquid ammonia is used as reagents. Clemmensen Reduction : Birch Reduction: Reduces carbonyl groups to methylene groups. 4. It is a method for the reduction of aromatic rings using alkali metals (usually sodium or lithium) in liquid ammonia. 2. Arndt-Eistert reduction Hydrocarbons Chemistry Practice questions, MCQs, Past Year Questions (PYQs), NCERT Questions, Question Bank, Class 11 and Class 12 Questions, NCERT Exemplar Questions and PDF Questions with answers, solutions, explanations, NCERT reference and difficulty level Birch reduction : Benzene can be reduced to 1, 4 - cyclohexadiene by treatment with Na or Li in a mixture of liquid ammonia and alcohol. Product: \( \text{cis-2-butene} \) Step 3: Reduction of 2-butyne with sodium in liquid ammonia The reduction of alkynes with sodium in liquid ammonia is known as the Birch reduction. For example, The Birch reduction is known as the chemical reaction where benzene is converted to 1,4-cyclohexadiene. 1 Study App and Learning App with Instant Video Solutions for NCERT Class 6, Class 7, Class 8, Class 9, Class 10, Class 11 and Class 12, IIT JEE prep, NEET preparation and CBSE, UP Board, Bihar Board, Rajasthan Board, MP Board, Telangana Board etc Step-by-Step Solution: 1. 1 Study App and Learning App with Instant Video Solutions for NCERT Class 6, Class 7, Class 8, Class . 1 Study App and Learning App with Instant Video Solutions for NCERT Class 6, Class 7, Class 8, Class 9, Class 10, Class 11 and Class 12, IIT JEE prep, NEET preparation and CBSE, UP Board, Bihar Board, Rajasthan Board, MP Board, Telangana Board etc Birch Reduction/Arenes/Conjugated Dienes/Organic Chemistry/B. Maths Jul 21, 2023 · Birch reduction of aniline will produce : b y Ask Doubtnut is No. The reagent is a mixture of sodium and lithium metal in an organic solvent. NCERT Solutions For Class 12. The reagent is named after its inventor, Arthur Birch. Birch reduction involves radical anion and radical formation in its mechanism. This is known as Birch reduction. The reaction involves the oxidation of toluene with chromyl chloride (CrO 2 Cl 2) in CCl 4. The mechanism involves the reduction of a carbonyl group to a methylene group with the use of a Birch reduction reagent. Clemmensen's reduction 2. Understanding Birch Reduction : Birch reduction is a chemical reaction that involves the reduction of aromatic compounds to form non-aromatic compounds, typically using alkali metals in liquid ammonia. Videos you watch may be added to the TV's watch history and influence TV recommendations. 8 rating on its app. Etard’s Reaction. /Masters of Chemistry/NET-JRF/GATE/SET/12th/CBSE/State Board/NCERT 1,4 addition take place. For example, May 17, 2023 · For better understanding, Birch Reduction of benzene is explained below: In birch reduction, benzene reacts with sodium or potassium or lithium metal in the presence of alcohol and it converts into 1,4-cyclohexadiene. You're signed out. Jul 3, 2023 · It is possible to stop the reduction at the alkene stage by using specific catalysts such as Lindlar’s catalyst i. Then find a+b by Chemistry experts to help you in doubts & scoring excellent marks in Class 12 exams. 4-dihydro cyclohexadiene and naphthalene gives 1, 4-dihydronaphthalene. 0. Birch reduction of benzene will produce 1,4-cyclohexadiene. The Birch reduction can be classified as an When aromatic rings are reduced with sodium, potassium or lithium in liquid ammonia or amine in the presence of alcohol, addition of hydrogen takes place at posilions-1 and -4 to give an unconjugated diene. Maths Apr 9, 2025 · If playback doesn't begin shortly, try restarting your device. It is used for partial reduction of alkynes to trans-alkenes. It follows a carbenoid mechanism. Zinc amalgam is used as a reagent. We also provide extensive NCERT solutions, sample papers, NEET, JEE Mains, BITSAT previous year papers, which makes us a one-stop solution for all resources. Wolff-kishner Reduction Practice questions, MCQs, Past Year Questions (PYQs), NCERT Questions, Question Bank, Class 11 and Class 12 Questions, NCERT Exemplar Questions and PDF Questions with answers, solutions, explanations, NCERT reference and difficulty level When 2-butyne is treated with Lindlar's catalyst, the triple bond is reduced to a double bond, resulting in the formation of cis-2-butene. The Birch reduction of benzoic acid gives: Doubtnut is No. , under one set of given conditions, it gives only one stereo-isomer. 5 million registered students and over 78 lakh+ Youtube subscribers with 4. The process of this reaction, which is known as dissolving metal reduction or birch reduction, involves a radical mechanism and yields a trans-alkene as a result. Ethanol is used as a solvent. NCERT solutions. →N2H4/KOH; Reaction is known as 1. Birch reduction of nitrobenzene will produce : Doubtnut is No. To avoi Nov 21, 2024 · Which reagent is used in Birch reduction? Answer: Na / liquid NH 3, ethanol. In the Birch reduction, aromatic compounds undergo a transformation into 1,4-cyclohexadienes. Physics Wallah also caters to over 3. It follows a free Doubtnut is No. neet Which of the following are examples of Birch reduction? see full answer. Arndt-Eistert reduction Hydrocarbons Chemistry Practice questions, MCQs, Past Year Questions (PYQs), NCERT Questions, Question Bank, Class 11 and Class 12 Questions, NCERT Exemplar Questions and PDF Questions with answers, solutions, explanations, NCERT reference and difficulty level Fisher-Spier reduction 3. 1 Study App and Learning App with Instant Video Solutions for NCERT Class 6 Ncert Solutions English Medium. The reaction was first described by Arthur Birch in 1944. Number of active methylene hydrogens present in X = a and in Y = b . Thus, benzene gives 1. In the conversion of alkyne to trans-alkene by Birch reduction using alkali metals (such as Na or K) in liquid N H 3 and alcohol Birch reduction : Birch reduction involves controlled reduction of alkynes & atomic compounds in the preseance of alkali metals & alcohol. Fisher-Spier reduction 3. Birch reduction 4. C. 1 Study App and Learning App with Instant Video Solutions for NCERT Class 6, Class 7, Class 8, Class 9, Class 10, Class 11 and Class 12, IIT JEE prep, NEET preparation and CBSE, UP Board, Bihar Board, Rajasthan Board, MP Board, Telangana Board etc Doubtnut is No. In simple words, the Birch reduction reaction is an organic redox reaction used to convert aromatic compounds into dienes. Rosenmunds Reduction 4. It provides a method to sterospecifically prepare alkenes of E- configuration R − C ≡ C − R M, E t O H − −−−− → The characteristic type of reaction of alkynes is electrophilic addition The Birch reduction of benzoic acid gives:- (a) (b) (c) (d) Practice questions, MCQs, Past Year Questions (PYQs), NCERT Questions, Question Bank, Class 11 and Class 12 Questions, NCERT Exemplar Questions and PDF Questions with answers, solutions, explanations, NCERT reference and difficulty level Reduction of unsaturated compounds with active metals such as Li, Na, K, etc. Birch Reduction of Alkynes. This reduction is stereoselective, i. According to the above diagram, the mechanism of birch reduction of benzene is associated with the following three steps: Jul 21, 2023 · Doubtnut is No. This reaction introduces two hydrogen atoms at opposite ends of the aromatic ring. The reaction is named after the Australian chemist Arthur Birch. 1 Study App and Learning App with Instant Video Solutions for NCERT Class 6, Class 7, Class 8, Class 9, Class 10, Class 11 and Class 12, IIT JEE prep, NEET preparation and CBSE, UP Board, Bihar Board, Rajasthan Board, MP Board, Telangana Board etc Jul 21, 2023 · Doubtnut is No. cyclohexadienes. Reduces arenes to . Identifying the Reducing Agent : The key component of Birch reduction is the reducing agent. It is a very useful reaction in synthetic organic chemistry. The Birch reduction of benzoic acid gives : - In the Birch reduction, the triple bond of the alkyne undergoes reduction. Feb 17, 2025 · #whatisbirchreduction #ncertchemistryclass12 #ncertchemistryclass11 #reagentsofbirchreduction #mechanismofbirchreduction #hydrocarbons #ncertchemistryclass11 What is Birch Reduction? The Birch reduction is an organic chemical reaction where aromatic compounds which have a benzenoid ring are converted into 1,4-cyclohexadiene which have two hydrogen atoms attached at opposite ends of the molecule. The Birch reduction of toluene gives:\n \n \n \n \n . In arenes, 1, 4 Addition of hydrogen atoms occurs. Catalytic reduction of alkynes with dihydrogen in presence of Lindlar’s catalyst always gives cis- alkenes. The reduction process occurs in the presence of liquid ammonia and sodium (Na), leading to the formation of radical anions when solvated electrons are introduced to the 1,4 addition take place. NCERT Solutions For Class 11 Chemistry Chapter 13 Hydrocarbons Fill In The Blanks. On ozonolysis followed by reduction with Dimethyl sulphide 2 product are obtained X&Y . Note: This is a trans addition and alkynes give trans alkenes in the Birch reduction. . Similar questions. Apr 9, 2025 · If playback doesn't begin shortly, try restarting your device. b y Download Allen App Login Jul 21, 2023 · NAReduction of Alkyne (Birch & Lindlars) Reduction of an alkyne to the double bond stage can yield a cis alkene or trans alkene (except in cases where triple bond is at the end of the chain ) Reduction of alknes with sodium or lithium in liquid N H 3 yields predominantly trans alkene. This reaction is also very important for the reduction of aromatic and non-aromatic moieties. The selective reduction of aromatic and non-aromatic moieties makes it useful for multi-step total synthesis processes. Birch reduction is sometimes the only key for the reduction of several naturally occurring compounds. About Wolf Kishner Reduction This is a selective reduction it can reduce only carbonyl compounds unable to reduce the OH group. /Graduation/Chemistry/M. 1 Study App and Learning App with Instant Video Solutions for NCERT Class 6, Class 7, Class 8 NCERT Solutions. About Etard’s Reaction. In the case of side chains bigger than CH 3 group the end carbon atom of the chain is oxidized by CrO 2 Cl 2 to –CHO group. About Press Copyright Contact us Creators Advertise Press Copyright Contact us Creators Advertise Fisher-Spier reduction 3. Arndt-Eistert reduction Hydrocarbons Chemistry Practice questions, MCQs, Past Year Questions (PYQs), NCERT Questions, Question Bank, Class 11 and Class 12 Questions, NCERT Exemplar Questions and PDF Questions with answers, solutions, explanations, NCERT reference and difficulty level A, C are perfect examples of Birch reduction, because electron donating groups always appear on one side of double bonded . Birch reduction occurs by the reaction of an aromatic arene with metal dissolved in ammonia and in the presence of alcohol. When a ketone or an aldehyde is heated in a basic solution of hydrazine, the carbonyl group is converted to a methylene group this process is called Deoxygenation because an oxygen is removed from the reactant. Class 12 NCERT Solutions; Class 11 NCERT Solutions; The Birch reduction of benzoic acid gives:- (a) (b) (c) (d) Aldehydes, Ketones and Carboxylic Acids Chemistry Questions Practice questions, MCQs, Past Year Questions (PYQs), NCERT Questions, Question Bank, Class 11 and Class 12 Questions, NCERT Exemplar Questions and PDF Questions with answers, solutions, explanations, NCERT reference and difficulty level →N2H4/KOH; Reaction is known as 1. The sodium donates electrons, and in the presence of liquid ammonia, protons (H⁺) are added to the alkene formed. Hydrochloric acid is used as a solvent. Class 6. The Birch reduction mechanism is an important step in organic synthesis. 1 Study App and Learning App with Instant Video Solutions for NCERT Class 6, Class 7, Class 8 The Birch reduction of benzoic acid gives:- (a) (b) (c) (d) Aldehydes, Ketones and Carboxylic Acids Organic Chemistry Practice questions, MCQs, Past Year Questions (PYQs), NCERT Questions, Question Bank, Class 11 and Class 12 Questions, NCERT Exemplar Questions and PDF Questions with answers, solutions, explanations, NCERT reference and difficulty level Jul 21, 2023 · Birch reduction of nitrobenzne will produce : b y Doubtnut is No. When an alkyne pi bond is treated with sodium or lithium metal dissolved in ammonia, the anti-addition of hydrogen occurs. Jul 3, 2020 · The Birch reduction is a chemical reaction named after the Australian chemist Arthur Birch. Suggest Corrections. Reaction Reduction of alkynes with sodium in liquid ammonia is called Birch reduction. On ozonolysis followed by reduction with Dimethyl sulphide 2 product are obtained X & Y. 1 Study App and Learning App with Instant Video Solutions for NCERT Class 6, Class 7, Class 8, Class 9, Class 10, Class 11 and Class 12, IIT JEE prep, NEET preparation and CBSE, UP Board, Bihar Board, Rajasthan Board, MP Board, Telangana Board etc Jul 21, 2023 · Ncert Solutions English Medium. Wolff-kishner Reduction Practice questions, MCQs, Past Year Questions (PYQs), NCERT Questions, Question Bank, Class 11 and Class 12 Questions, NCERT Exemplar Questions and PDF Questions with answers, solutions, explanations, NCERT reference and difficulty level Ncert Solutions English Medium. The mechanism for Birch’s reduction reaction is as given below: The ammonia (gas) at room temperature is condensed by lowering its temperature to -78 o C. Maths Named after Arthur Birch Reaction type Organic redox reaction I d e n ti fi e r s Organic Chemistry Portal birch-reduction RSC ontology ID RXNO:0000042 B i rc h re d u c ti on The Birch reduction is an organic reaction that is used to convert arenes to cyclohexadienes. Birch Reduction 3. For example, reduction of alkynes gives only trans - alkenes. 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